|
Lecturer(s)
|
-
Svoboda Ladislav, doc. Ing. CSc.
-
Bulánek Roman, prof. Ing. Ph.D.
|
|
Course content
|
Physical processes limiting technological processes. Difussion, 1. Fick's law. Noyes-Nernst's and Hixon-Crowel's equation, character of control process. Difussion in unsteady conditions, 2. Fick's law. Difussion in solid materials. New phase formation by crystallization of a solution or melt, growth of a new phase, Tamman's curves. Adsorption and desorption, adsorption izotherms, influence of temperature. Capillary condensation, porosity. Kinetics of homogeneous simultaneous chemical reactions. Principle of steady state. Theory of rate constant, temperature dependence of rate constant, order of chemical reaction. Kinetics of heterogeneous noncatalysed reactions. Kinetics of heterogeneous catalysed reactions, formal and model kinetic equations. Difussion mass transfer at heterogeneous catalysed reactions, internal and external difussion. Catalysts, their properties, preparation and mechanism of effect. Bases of calculations of reactors. Batch and flow ideally stirred reactors. Flow reactor with a piston-type flow. Nonizotermal mode of reactors.
|
|
Learning activities and teaching methods
|
|
unspecified, Stimulating activities (simulation, games, drama)
|
|
Learning outcomes
|
An extension of knowledge in the field of reaction kinetics by parts indispensable for students of Inorganic technology, such as physical processes limiting kinetics of technological chemical processes, kinetics of heterogeneous reactions and principles of reactor calculations.
Graduate of the subject is equipped with knowledge of technical physical chemistry, especially applied reaction kinetics, required at various working positions in chemical industry, research & development, education and other fields of national economy.
|
|
Prerequisites
|
Knowledge of physical chemistry, chemical engineering and mathematics on bachelor level.
|
|
Assessment methods and criteria
|
Oral examination, Written examination
Three calculation tests are written during the term, the course is closed by written test and oral exam. To admit to oral exam it is necessary to succeed in all tests and in written part of exam.
|
|
Recommended literature
|
-
Atkins P., Paula J. Fyzikální chemie, 9. vydání. VŠCHT Praha, 2013.
-
Cussler E. L. Diffusion, Mass Transfer in Fluid Systems. Cambridge University Press, Cambridge, 2000.
-
Ilavský a kol. Aplikovaná chemická kinetika a teória reaktorov I. Alfa, Bratislava, 1990.
-
Šolc Z., Velich V. Aplikovaná reakční kinetika. VŠCHT Pardubice, 1989.
-
Thomas J. M., Thomas W. J. Principles and Practice of Heterogeneous Catalysis. VCH, Weinheim, 1997.
-
Van Santen R. A. (Ed.). Catalysis: An Integrated Approach. Elsevier, Amsterdam, 1999.
-
West A.R. Basic Solid State Chemistry. John Wiley, Chichester, 1999.
-
Wilkinson D.S. Mass Transport in Solids and Fluids. Cambridge University Press, Cambridge, 2000.
|