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Lecturer(s)
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Bulánek Roman, prof. Ing. Ph.D.
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Martinéz de Yuso Alicia, Dr.
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Course content
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Theory of adsoption forces - physisorption and chemisorption, kinetics and thermodynamics of adsorption on solid surfaces, theory of adsorption equilibrium - monolayer adsorption, theory of adsorption equilibrium - multilayer adsorption, capillary condensation, Volumetry/manometry, gravimetry, chromatography and spectroscopic methods of adsorbed amount determination - apparatuses and principles of measurement, temperature programmed techniques - theory of non-isothermal methods, evaluation of surface area and porosity of materials, technical use of adsorption - separation and purification of substances
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Learning activities and teaching methods
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Work with text (with textbook, with book)
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Learning outcomes
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Enhance and improve knowledge of students on adsorption phenomenon, theoretical description of these processes and experimental methods of adsorption study are the main aims of the course. Students will have possibilities to work with real experimental data, they will make data processing for determination of surface areas, texture of solids and physical and chemical properties of adsorption centers.
Student will obtain overview about theory of adsorption forces and equilibrium and, in addition, instrumental techniques exploited in measurement and study of surface phenomenons. Graduation of this course is basic presumption for study of other courses of both study program Technical physical chemistry and other specialization like inorganic, organic and analytical chemistry.
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Prerequisites
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Student must pass out bachelor degree and evidence basic knowledge of physical chemistry.
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Assessment methods and criteria
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Oral examination
Exam is oral. Basic form of exam is discussion of choice topics. Knowledge, conceptions and application skills are examined. Knowledge is check up by solution of theoretical and numerical problems during semester.
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Recommended literature
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A. Tockstein. Základy fyzikální chemie I, skripta VSCHT Pardubice. Univerzita Pardubice, 1995.
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A. Tockstein. Základy fyzikální chemie II, 1996, Univerzita Pardubice. Univerzia Pardubice, 1996.
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Atkins P. W. ¨Physical chemistry, Oxford University Press, Oxford 1989 U.K.. Oxford University Press, Oxford, 1989.
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Laider K. J., Meiser J. H., Sanctuary B. C. Physical Chemistry. Houghton Miffin Company, New York, 2003.
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Moore W. J. Fyzikální chemie, SNTL Praha 1979. SNTL Praha, 1979.
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Niemantsverdriet J. W. Spectroscopy in catalysis. VCH, New York, 1995.
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Paryjczak T. Gas Chromatography in Adsorption and Catalysis. PWN Waršava, 1986.
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Ponec V., Knor Z., Černý S. Adsorpce na tuhých látkách. SNTL Praha, 1968.
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Rouquerol F., Rouquerol J., Sing K. Adsorption by Powders and Porous Solids. Academic Press, San Diego, 1999.
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Van Santen R. A., Van Leeuwen P. W. N. M., Moulijn J. A., Averill B. A. Catalysis: an Integrated Approach. Academic Press, San Diego, 1999.
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