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Lecturer(s)
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Vrána Jan, Ing. Ph.D.
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Hostinský Tomáš, Ing. Ph.D.
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Dostál Libor, prof. Ing. Ph.D.
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Erben Milan, doc. Ing. Ph.D.
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Vinklárek Jaromír, prof. Ing. Dr.
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Schwarz Jiří, Ing. Ph.D.
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Ruleová Pavlína, Ing. Ph.D.
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Střižík Lukáš, Ing. Ph.D.
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Course content
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1. Theoretical introduction, division into tables, work safety, explanation of coordination compounds, explanation of tasks. 2. Preparation of nickel complexes - [Ni(NH3)6]Cl2, NiCl2 3. Preparation of copper complexes - CuCl, [Cu(H2O)2(salic)2].2H2O, [Cu(py)2(salic)2] 4. Preparation of complexes of cobalt-trans-[Co(en)2(NO2)2]NO3, Co[Hg(SCN)4] 5. Preparation of chromium complexes - K3[Cr(ox)3].3H2O, [Cr(en)2(ox)][Cr(en)(ox)2]. 2H2O 6. Preparation of potassium hexacyanoferrate - K3[Fe(CN)6] 7. Preparation of acetylacetonates of chromium and vanadium - Cr(acac)3, VO(acac)2, I.RPP 8. Preparation of cobaltite complexes - [Co(NH3)5Cl]Cl2, [Co(Hdmg)2Cl(py)] 9. Ion exchangers - CuCl2, CuCO3.Cu(OH)2 10. Preparation of potassium dichromate - K2Cr2O7 11. Separation of cations by paper chromatography Determination of Rf, proof of cations in the mixture 12. Preparation of "Mohr's" salt - (NH4)2Fe(SO4)2.6H2O 13. Extraordinary compensations, II. RPP, awarding credit Continuous control using written tests (90 min) in the 8th and 13th week.
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Learning activities and teaching methods
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Laboratory work
- Home preparation for classes
- 25 hours per semester
- Preparation for a credit (assessment)
- 5 hours per semester
- Participation in classes
- 70 hours per semester
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Learning outcomes
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Laboratory Practice of General and Inorganic Chemistry II is continuation of Laboratory Practice of General and Inorganic Chemistry I. This course aimed in learning advanced laboratory techniques and preparations.
After completing the course, the student is able to prepare complex and coordinating inorganic compounds using basic and more demanding laboratory techniques.
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Prerequisites
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Fundamental theoretical and mathematical knowledge from general and inorganic chemistry. Passing out the course Laboratory Practice of General and Inorganic Chemistry I.
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Assessment methods and criteria
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Oral examination, Written examination
During the laboratories, the preparation for the laboratories is checked using continuous written tests and oral examinations of individual students. Students submit the final products of their experimental work for inspection, which they then process in writing in the form of a protocol. Experimental results, interim control results and evaluations from the final written and oral exam are included in the overall assessment.
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Recommended literature
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Handlíř K., Mošner P., Nádvorník M., Vlček M. Laboratorní cvičení z obecné chemie..
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Handlíř K., Nádvorník M., Vlček M. Laboratorní cvičení z anorganické chemie.
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Handlíř K., Nádvorník M., Vlček M. Výpočty a cvičení z obecné a anorganické chemie I..
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Klikorka J., Klazar J., Horák J., Votinský J. Základy preparativní anorganické chemie. III. vydání, SNTL, Praha 1974..
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Nádvorník M., Handlíř K. .: Návody pro laboratorní cvičení z předmětu "Chemie organokovových sloučenin". Interní skriptum katedry obecné a anorganické chemie. 45 s. FCHT, Univerzita Pardubice 1994. Upravené vydání 2000, k disposici též na katedrálních webových stránkách..
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Rendle P., Vokins M., Davis P. Experimental Chemistry. A Laboratory Manual. Second Edition, E. Arnold Ltd., London 1972..
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