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Lecturer(s)
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Holubová Jana, doc. RNDr. Ph.D.
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Course content
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Basic physical principles of nuclear magnetic resonance (NMR) and electron spin resonance (ESR) and selection rules. NMR: solid state NMR techniques, magic angle spinning (MAS) and measurement of static spectra, basic characteristics of spectra and their significance - chemical shift, line width and shape and their relation to the studied core. Nuclei with spin ? and problems of measurement and analysis of spektra of quadrupole nuclei. ESR: basic characteristics of spectra and their significance, spectra of monocrystals, spectra of powder and glass materials, their shape and analysis, determination of g factor and hyperfine splitting constant and their relationship to symmetry and distribution of electron density in the studied atom environment. Possibilities of computer simulation of NMR and ESR spectra.
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Learning activities and teaching methods
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Dialogic (discussion, interview, brainstorming)
- Preparation of a presentation (report)
- 30 hours per semester
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Learning outcomes
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The student will gain advanced knowledge of methods for measuring and analyzing solid state NMR and EPR data.
Understanding the principle of the lectured methods and the possibility of interpreting at least simpler experimental results.
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Prerequisites
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Basic knowledge of the principle of both methods at the level of the subject Metody studia látek I and Laboratory of Characterization of Materials (follow-up master's study).
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Assessment methods and criteria
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Home assignment evaluation, Discussion
Teaching takes place in the form of consultations. PhD student processes given topic in written form as a basis for subsequent discussion.
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Recommended literature
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Atkins P. W. Fyzikálna chémia (vybrané kapitoly), 1999, Oxford/STU v Bratislavě..
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Gordy, Walter. Theory and applications of electron spin resonance. New York: Wiley-Interscience, 1980.
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MacKenzie, Kenneth J. D. Multinuclear solid-state NMR of inorganic materials. Amsterdam: Elsevier Science, 2002. ISBN 0-08-043787-7.
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Rieger, Philip H. Electron spin resonance : analysis and interpretation. Cambridge: Royal Society of Chemistry, 2007. ISBN 978-0-85404-355-2.
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Symons, Martyn. Chemical and biochemical aspects of electron-spin resonance spectroscopy. New York: Van Nostrand Reinhold, 1978.
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