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Lecturer(s)
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Zeman Svatopluk, prof. Ing. DrSc.
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Jalový Zdeněk, doc. Ing. Ph.D.
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Course content
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Nitration agents. Aromatic nitration, properties of nitroarenes. Processes, safety, economy of production, technology of arenes mononitration. Polynitroarenes, polynitroarenes thermal stability theory, thermally stable nitroarenes. Nitroparafines, physically-chemical properties, mononitration mechanism. Nitroparafines (geminal, vicinal), synthetic methods for important nitroparafines. Nitramines, nitrating agent for nitramines, N-nitration of sec-amines, N-Mannich condensations and nitrolysis of the condensation products, technology of important cyclic nitramines. Nitrosoamines. Nitric acid esters. Technology of liquid, solid and polymeric esters of nitric acid. Anorganic nitrates. Prime explosives, history, requirements for prime explosives properties, technology of manufacture. Types of prime explosives.
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Learning activities and teaching methods
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Monologic (reading, lecture, briefing)
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Learning outcomes
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To introduce main types of chemical reactions used for production of energetic materials. To introduce methods of preparation, basic properties, application and safety characteristics of individual types of energetic materials.
Student obtains knowledge about individual groups of energetic materials, their method of preparation, technology, application and limitations in the use due to their power, sensitivity, stability and toxicity.
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Prerequisites
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C001 General and inorganic chemistry C008 Organic chemistry C021 Chemical engineering C893 Explosion physics I
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Assessment methods and criteria
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Oral examination
Oral exam.
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Recommended literature
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Bagal, L.I.:. Chimija i technologija inicijuščich vzryvščatych veščestv. 1975 Mašinostrojenie, Moskva..
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Cooper, P.W. Explosives Engineering, 1996 Wiley, N.Y..
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Denkstein, J. Chemie a technologie výbušin.,Učební texty pro licenční studium 1987, Univerzita Pardubice, Pardubice..
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Kolektiv:. Speciální technika, díl I. Federální ministerstvo všeobec. strojírenství 1976, Praha..
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Kolektiv:. Ullman´s Encyklopedia of Industrial Chemistry, Vols. A6 and A17 VCH Verlagsgesellschaft, Weinheim.
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Orlova, E.Ju. Chimija i technologija brizantnych vzryvčatych veščesv. 1981 Izdat. Chimija, Leningrad..
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Urbanski, T. Chemistry and Technology of Explosives. Vols. 1, 2, 3 and 4, 1986 Pergamon Press, Oxford..
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ZEMAN S. Třaskaviny, Sylaby přednášek 2000, Univerzita Pardubice.. Univerzita Pardubice, 2007. ISBN 978-80-7194-939-8.
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