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Lecturer(s)
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Váňa Jiří, doc. Ing. Ph.D.
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Hanusek Jiří, prof. Ing. Ph.D.
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Course content
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Importance of chemical kinetics and reaction mechanisms. Theory of reaction rates. Physical and chemical methods used for determination of rate and equilibrium constants. Study of kinetics of various types reactions (reactions of 1. and 2. order, paralel and consecutive reactions...) Acid-base catalysis Influence of medium upon chemical reactivity Linear free energy relationships
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Learning activities and teaching methods
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Monologic (reading, lecture, briefing)
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Learning outcomes
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The aim of this subject is to apprise students with physico-chemical methods used in organic chemistry for study of the chemical reactions course. The emphasis is put mainly on understanding of principles of particular methods and on correct interpretation of obtained physico-chemical quantities.
After passing the subject the student is able to choose suitable experimental technique for study of relationships between structure and reactivity of organic compounds a to evaluate obtained physico-chemical data.
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Prerequisites
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Basic knowledge gained in subjects: Basics of physical chemistry and Organic chemistry.
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Assessment methods and criteria
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Oral examination
Oral examination and written test.
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Recommended literature
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Isaacs N.:. Physical Organic Chemistry, Longman Essex 1995..
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Anslyn E. V., Dougherty D. A.:. Modern Physical Organic Chemistry, University Science Books, Sausalito 2006..
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Bekárek V., Nevěčná T.:. Rozpouštědlové vlivy v chemii a jejich hodnocení, Academia Praha 1992..
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Exner O.:. Korelační vztahy v organické chemii, SNTL Praha 1981..
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Hanusek J. Přednášky z Fyzikální organické chemie (v *.pdf).
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Page M., Williams A.:. Organic & Bioorganic Mechanisms, Longman Singapore 1997..
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Reichardt Ch.:. Solvents and Solvent Effects in Organic Chemistry, Wiley WCH, Weinheim 2003..
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Williams A:. : Free energy relationships in organic and bio-organic chemistry, Royal Society of Chemistry, Cambridge 2003..
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