Week 1: Introduction, historical milestones and personalities of macromolecular chemistry, basic concepts, constitution and nomenclature of polymers, configurational isomerism, stereoisomerism, characteristic properties of macromolecular substances, definitions of oligomer and polymer according to IUPAC. Week 2: Molecular weight of polymers and principles of experimental determination, properties of isolated macromolecules, conformational isomerism, dissolution of polymers. Week 3: Cohesion of macromolecules, supramolecular structures of polymers, physical and phase states of polymers, semi-crystalline character of polymers, viscoelasticity. Week 4: Prerequisites for polymerizability of low-molecular substances, step polymerization, the kinetics of step polymerizations, characteristic features of step polymerizations, the functionality of monomers, polycondensation reactions of bifunctional substances, the relationship between conversion and degree of polymerization in linear polycondensations, equilibrium polycondensations, equilibrium constant and achievable conversion. Week 5: Network formation in step polymerization, non-equilibrium polycondensations, polycondensation reactions of formaldehyde and phenols, interfacial polycondensations, polyaddition, examples of polymers formed by step polymerization. Week 6: Chain polymerizations, radical polymerization, mechanism, elementary steps of radical polymerization, kinetics of radical polymerization in a homogeneous environment. Week 7: Radical copolymerization, copolymerization parameters, copolymerization diagrams. Week 8: Radical polymerization techniques in heterogeneous environments, block, solution, suspension, and emulsion polymerization. Week 9: Mechanism of emulsion polymerization, particle nucleation models, kinetics of emulsion polymerization. Week 10: Ionic polymerizations and ring-opening polymerizations, propagation, transfer, and termination reactions of cationic reactions, "living" anionic polymerizations, ionic polymerizations in nonpolar environments, and industrial applications. Week 11: Coordination polymerization, catalysts, and industrial applications. Week 12: Atom transfer radical polymerization (ATRP), mechanism, system components, preparation of functional polymers. Week 13: Natural polymers, polysaccharides, cellulose, starch, lignin, polyprenes, polypeptides.
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Jarušek, Jaroslav. Chemie filmotvorných látek.. Pardubice: Univerzita Pardubice, 1998. ISBN 80-7194-169-7.
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Mleziva J., Kálal J. Základy makromolekulární chemie. Praha: SNTL, 1986. ISBN 04-621-86.
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Mleziva, Josef. Polymery : výroba, struktura, vlastnosti a použití. Praha: Sobotáles, 2000. ISBN 80-85920-72-7.
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Šňupárek, Jaromír. Makromolekulární chemie : úvod do chemie a technologie polymerů. Pardubice: Univerzita Pardubice, 2014. ISBN 978-80-7395-761-2.
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Šňupárek, Jaromír. Úvod do makromolekulární chemie. Pardubice: Univerzita Pardubice, 2003. ISBN 80-7194-562-5.
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