Tato práce se zabývá designem, syntézou, charakterizací a fyzikálně-chemickými
vlastnostmi push-pull chromoforů založených na indan-1,3-dionu. Všechny cílové
chromofory byly připraveny Knoevenagelovou kondenzací a následně Suzukiovou-
Miyaurovou nebo Sonogashirovou cross-coupling reakcí. Jejich struktura a
vlastnosti byly zkoumány pomocí rentgenové analýzy, elektrochemie, UV/Vis
absorpční spektroskopie, diferenční skenovací kalorimetrie, elektrickým polem
indukované druhé harmonické generace (EFISHG) studie a DFT výpočty. Byly
vyvozeny vztahy typu struktura-vlastnosti.
Anotace v angličtině
This work deals with the design, synthesis, characterization and physico-chemical properties of indane-1,3-dione based push-pull chromophores. All target chromophores were prepared via. knoevenagel condensation followed by Suzuki-Miyaura or Sonogashira cross-coupling reaction. Their structure and properties were further investigated by X-ray analysis, electrochemistry, UV/Vis absorption spectroscopy, differerential scanning calorimetry, electric-fild-induced second-harmonic generation (EFISHG) studies and DFT calkulations. Structure-property relationships were elucidated.
Tato práce se zabývá designem, syntézou, charakterizací a fyzikálně-chemickými
vlastnostmi push-pull chromoforů založených na indan-1,3-dionu. Všechny cílové
chromofory byly připraveny Knoevenagelovou kondenzací a následně Suzukiovou-
Miyaurovou nebo Sonogashirovou cross-coupling reakcí. Jejich struktura a
vlastnosti byly zkoumány pomocí rentgenové analýzy, elektrochemie, UV/Vis
absorpční spektroskopie, diferenční skenovací kalorimetrie, elektrickým polem
indukované druhé harmonické generace (EFISHG) studie a DFT výpočty. Byly
vyvozeny vztahy typu struktura-vlastnosti.
Anotace v angličtině
This work deals with the design, synthesis, characterization and physico-chemical properties of indane-1,3-dione based push-pull chromophores. All target chromophores were prepared via. knoevenagel condensation followed by Suzuki-Miyaura or Sonogashira cross-coupling reaction. Their structure and properties were further investigated by X-ray analysis, electrochemistry, UV/Vis absorption spectroscopy, differerential scanning calorimetry, electric-fild-induced second-harmonic generation (EFISHG) studies and DFT calkulations. Structure-property relationships were elucidated.
ZÁPIS O OBHAJOBĚ DISERTAČNÍ PRÁCE
(Record concerning Ph.D. Thesis Defense)
Competitor: MSc. Parmeshwar B. Solanke
Ph.D. Thesis title: "Synthesis and properties of model push-pull systems based on indane-1,3-dione"
Presence: see enclosed Attendance Sheet
Thesis defense was opened by the Chairman of the Committee - prof. Ing. Jiří Kulhánek, Ph.D. - who stated that from six designated Committee members including two opponents is five present thus allowing accomplishment of the thesis examination. Further he excused Prof. RNDr. Pavol Zahradník who cannot come to join the Committee due to his illness. Thesis Supervisor - Assoc. prof. Ing. Filip Bureš, Ph.D. - has also attended the defense. The Chairman briefly introduced competitor and announced that he fulfilled all the necessary requirements according to Study and Examination Rules of the Faculty of Chemical Technology, University of Pardubice. The Chairman also announced that the Competitor passed his Comprehensive PhD Examination (State Doctoral Examination - October 7th 2014). Then thesis supervisor apprised Committee with his positive formal opinions. Subsequently, the positive opinions of Head of Institute of Organic Chemistry and Technology - prof. Ing. Miloš Sedlák, DrSc. - has been read by the secretary of the Committee.
Competitor Parmeshwar Solanke then gave a 25 minutes lecture about results obtained during his study. His lecture was appreciated by the Committee members. After that, opponents' expert opinions have been read; Assoc. prof. Sylvain Achelle read his opinions and secretary of the committee read the opinions of Prof. RNDr. Pavol Zahradník. Opponents asked Competitor for appropriate answers. Competitor successfully answered all opponents' questions and suggestions.
Then PhD. Thesis Examination was opened for discussion:
" prof. Ing. Miroslav Ludwig, CSc.
- Using of various longer linkers.
- Problems with synthesizing of certain molecular skeletons.
" prof. Ing. Dalimil Dvořák, CSc.
- Aspects of the decomposition of Y-shaped compounds.
- Boronic acid derivatives.
" Assoc. prof. Ing. Petr Šimůnek, Ph.D.
- Application and comparison of the molecular NLO properties.
" Assoc. prof. Dr. Sylvain Achelle
- HOMO / LUMO gaps and their correlation.
Competitor successfully answered all Committee-members' questions and suggestions.
Neither written or oral questions nor remarks were delivered to the Chairman of the Committee, therefore the public part of the Defense was closed.
After that, all Committee members voted using printed forms (they are attached to this Record). On the basis of the voting the Chairman has announced that the result is:
"passed" (vyhověl).
At the end of session the chairman apprised Competitor with the result of voting and then announced that he will suggest to Dean of Faculty of Chemical Technology (prof. Ing. Petr Kalenda, CSc.) the Ph.D. graduation of Parmeshwar Solanke.
In Pardubice, October 27th 2015.
Chairman of the Committee: prof. Ing. Jiří Kulhánek, Ph.D.
prof. Ing. Miroslav Ludwig, CSc.
Assoc. prof. Ing. Petr Šimůnek, Ph.D.
prof. Ing. Dalimil Dvořák, CSc.
Opponent: Assoc. prof. Dr. Sylvain Achelle
Secretary of the Committee: Ing. Břetislav Brož