Reakcemi výchozího guanidínu [N,N?-bis-Dipp-N??-LNN]H2 (Dipp = 2,6-di(i-propyl)-
fenyl; LNN = 2[(dimethyl)aminomethyl]phenyl]) s organokovovými činidly Li, K, Mg, Zn,
Al. Byly připraveny jednou deprotonované guanidinátové komplexy, ale také bisguanidinátové
komplexy {[N,N?-bis-Dipp-N??-LNN]H}2Mg a {[N,N?-bis-Dipp-N??-LNN]-
H}2Zn.
Anotace v angličtině
Reactions of starting guanidine [N,N?-bis-Dipp-N??-LNN]H2 where (Dipp is 2,6-di(ipropyl)
phenyl; LNN is 2[(dimethyl)aminomethyl]phenyl]) with Li, K, Mg, Zn, Al organometallic
reagents were performed. New monodeprotonated heteroleptic complexes of all
elements and bis-guanidinato complexes of composition {[N,N?-bis-Dipp-N??-LNN]H}2Mg
and {[N,N?-bis-Dipp-N??-LNN]H}2Zn were prepared.
Reakcemi výchozího guanidínu [N,N?-bis-Dipp-N??-LNN]H2 (Dipp = 2,6-di(i-propyl)-
fenyl; LNN = 2[(dimethyl)aminomethyl]phenyl]) s organokovovými činidly Li, K, Mg, Zn,
Al. Byly připraveny jednou deprotonované guanidinátové komplexy, ale také bisguanidinátové
komplexy {[N,N?-bis-Dipp-N??-LNN]H}2Mg a {[N,N?-bis-Dipp-N??-LNN]-
H}2Zn.
Anotace v angličtině
Reactions of starting guanidine [N,N?-bis-Dipp-N??-LNN]H2 where (Dipp is 2,6-di(ipropyl)
phenyl; LNN is 2[(dimethyl)aminomethyl]phenyl]) with Li, K, Mg, Zn, Al organometallic
reagents were performed. New monodeprotonated heteroleptic complexes of all
elements and bis-guanidinato complexes of composition {[N,N?-bis-Dipp-N??-LNN]H}2Mg
and {[N,N?-bis-Dipp-N??-LNN]H}2Zn were prepared.