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Course info
UCHTML / C888
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Course description
Department/Unit / Abbreviation
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UCHTML
/
C888
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Academic Year
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2023/2024
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Academic Year
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2023/2024
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Title
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Macromolecular Chemistry
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Form of course completion
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Examination
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Form of course completion
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Examination
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Long Title
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Macromolecular Chemistry - Mechanism and Kinetics of Polyreactions
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Accredited / Credits
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Yes,
6
Cred.
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Type of completion
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Combined
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Type of completion
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Combined
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Time requirements
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Lecture
2
[HRS/WEEK]
Seminar
1
[HRS/WEEK]
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Course credit prior to examination
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No
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Course credit prior to examination
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No
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Automatic acceptance of credit before examination
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No
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Included in study average
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YES
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Language of instruction
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Czech
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Occ/max
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|
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Automatic acceptance of credit before examination
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No
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Summer semester
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2 / -
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0 / -
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0 / -
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Included in study average
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YES
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Winter semester
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0 / -
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0 / -
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0 / -
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Repeated registration
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NO
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Repeated registration
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NO
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Timetable
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Yes
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Semester taught
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Summer semester
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Semester taught
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Summer semester
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Minimum (B + C) students
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not determined
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Optional course |
Yes
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Optional course
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Yes
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Language of instruction
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Czech
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Internship duration
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0
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No. of hours of on-premise lessons |
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Evaluation scale |
A|B|C|D|E|F |
Periodicity |
každý rok
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Periodicita upřesnění |
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Fundamental theoretical course |
Yes
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Fundamental course |
Yes
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Fundamental theoretical course |
Yes
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Evaluation scale |
A|B|C|D|E|F |
Substituted course
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None
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Preclusive courses
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N/A
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Prerequisite courses
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N/A
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Informally recommended courses
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N/A
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Courses depending on this Course
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N/A
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Histogram of students' grades over the years:
Graphic PNG
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XLS
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Course objectives:
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The course explains mechanisms and kinetics of polymerization reactions, used in polymers manufacturing. Exercises are focused on simple calculations.
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Requirements on student
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2 tests Oral exam
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Content
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Polymerization reactions - step and chain processes..
Thermodynamics of polymerization reactions.
Ceiling temperature, polymerization-depolymerizaton equilibrium.
Condensation and addition polymerization, functionality of monomers, polymer architecture, gel point. Mechanisms and kinetics. Calculation of gel point (critical conversion) - Carothers, Flory.
Radical addition polymerization mechanism and kinetics.
Copolymerization - reactivity ratios,
Methods of radical polymerization.
Solution, suspension, emulsion polymerization.
Anionic, cationic and coordination polymerization.Living anionic polymerization.
Crosslinking of polymers - alkyds, unsaturated polyesters, polyurethanes, vulcanization.
Living radical polynerization - special polymerization processes - GTP, ATRP, SFRP, RAFT.
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Activities
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Fields of study
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Guarantors and lecturers
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-
Guarantors:
prof. Ing. Petr Kalenda, CSc. ,
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Lecturer:
prof. Ing. Petr Kalenda, CSc. (50%),
doc. Ing. Jana Machotová, Ph.D. (25%),
prof. Ing. Jaromír Šňupárek, DrSc. (25%),
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Seminar lecturer:
doc. Ing. Jana Machotová, Ph.D. (100%),
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Literature
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Basic:
Carraher C. E. Polymer Chemistry. Marcel Dekker, Basel, New York, 2003.
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Basic:
Rempp P., Merill E.W. Polymer Synthesis. Hüthig-Wepf Verlag, Basel, Heidelberg, New York., 1991.
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Basic:
Mleziva, Josef. Polymery : výroba, struktura, vlastnosti a použití. Praha: Sobotáles, 2000. ISBN 80-85920-72-7.
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Basic:
Bahadur P., Sastry N.V. Principles of Polymer Science. Alfa Science Int., Pangbourne, UK, 2002.
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Basic:
Mleziva J., Kálal J. Základy makromolekulární chemie. SNTL Praha, 1986. ISBN 04-621-86.
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Time requirements
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All forms of study
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Activities
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Time requirements for activity [h]
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Kontaktní výuka
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39
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Total
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39
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Prerequisites - other information about course preconditions |
Knowledge of organic, physical and macromolecular chemistry. |
Competences acquired |
Enlarged knoledge in macromolecular chemistry important for master degree study of Technology of Polymers Manufacturing and Processing. |
Teaching methods |
- Monologic (reading, lecture, briefing)
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Assessment methods |
- Oral examination
- Written examination
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