Course: Analytical Chemistry

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Course title Analytical Chemistry
Course code KALCH/C019
Organizational form of instruction Lecture + Seminar
Level of course Bachelor
Year of study not specified
Semester Summer
Number of ECTS credits 5
Language of instruction Czech
Status of course Compulsory
Form of instruction Face-to-face
Work placements This is not an internship
Recommended optional programme components None
Lecturer(s)
  • Eisner Aleš, Ing. Ph.D.
  • Husáková Lenka, doc. Ing. Ph.D.
  • Česlová Lenka, prof. Ing. Ph.D.
  • Bajer Tomáš, doc. Ing. Ph.D.
Course content
Introduction; Theoretical fundamentals of analytical chemistry Principles of qualitative analysis of inorganic compounds; Isolation and identification of selected ions Principles of quantitative analysis of inorganic compounds Complexing reactions, stability constants, effect of side reactions, shielding Chelatometric titrations, indicators, examples of applications including the selected mixtures determination Protolytic reactions, definitions of constants, pH, analytical application of protolytic reactions Acid-basic titrations, titration curves and their evaluation The modes of titration stop indication, examples of determinations; Titrations in non-water environment Precipitation reactions, solubility and solubility product, solubility affecting, precipitate properties, precipitate creation and condition selections for precipitation Examples of determinations, principles of precipitation titrations, indication, titration curves; Fundamentals of gravimetric analysis Red-ox reactions, standard and formal potential, effect of side reactions; Principles of most important oxidimetric and reductometric volumetric methods The course of red-ox titration curve, indication, typical examples of application Sample pretreatment - inorganic and organic samples, sampling, decomposition, pre concentration; Application for the environmental analysis and for analysis of working environment Expression of target compound content in solutions; Processing of analytical results Seminars: Solving redox equations. Preparation and concentration of solutions (mass percentages, substance concentration) and their mutual conversions. Calculations of simple direct titrations. Standardization of titration solutions. Indirect titrations (examples of volumetric analyses and standardization of titration solutions). Back titrations (principle and examples of volumetric analyses). Calculations of pH of strong acids and bases, weak acids and bases, salts, buffers. Calculation of pH in acid-base titrations (important points of the titration curve). Gravimetry. Solubility product, molar solubility, influence on the formation of precipitates, influence of pH on the formation of precipitates.

Learning activities and teaching methods
Monologic (reading, lecture, briefing)
Learning outcomes
The aim of this course is to supply information to students about fundamentals of chemical analysis, i.e. to introduce them the basic principles of qualitative and quantitative analyses of compounds.
Students after graduation of this course are able to orientate oneself in the field of qualitative and mainly quantitative analytical methods, is introduced with the principles of individual volumetric and gravimetric methods including the sample pre-treatment methods.
Prerequisites
High school knowledge of analytical chemistry
KOANCH/C002
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KOANCH/C222 and KALCH/C020
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KALCH/C020F
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KALCH/C020P
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KALCH/C619

Assessment methods and criteria
Oral examination, Written examination, Student performance assessment

The examination consists of written part followed by the oral examination. During the semester the gained knowledge of students from lectures and seminar practices are checked up and results are the part of the total classification. Current check of study - 10 % of grade, written part of examination - 25 %, demonstrate basic knowledge - 5 % oral examination - 60 %.
Recommended literature
  • 1. Skoog, D.A., West,D.M., Holler, J.F. Fundamentals of analytical chemistry, 1992, Saunders College Publishing..
  • 2. Gary, D. Christian:. Analytical Chemistry, 1994, New York, John Wiley & Sons.
  • 3. Bartoš, M., Šrámková, J., Staněk, V., Denver, F., Kalous, J. Analytická chemie I, 2004, Univerzita Pardubice..
  • 4. Holzbecher , Z., Churáček, J. a kol. Analytická chemie, 1987, SNTL Praha.
  • 5. Bartoš, M., Švancara, I., Šrámková, J. Laboratorní cvičení z analytické chemie I., 2004, Univerzita Pardubice..
  • 6. Garaj, J., Bustin, D., Hladký, Z. Analytická chémia, 1987, ALFA Bratislava.
  • 7. Vláčil, F. a kol. Příklady z chemické a instrumentální analýzy, 1978, 1983, SNTL Praha,; 1991, Informatorium Praha..
  • 8. Okáč, A. Analytická chemie kvalitativní, 1966, Academia Praha..


Study plans that include the course
Faculty Study plan (Version) Category of Branch/Specialization Recommended year of study Recommended semester